
Safety Data Sheet - Curb No.23
SAFETY DATA SHEET
2012 OSHA Hazard Communication Standard (HCS) (29 CFR 1910.1200)
Revision Number 1
Revision date 24-Jun-2021
Issuing Date 24-Jun-2021
1. PRODUCT AND COMPANY IDENTIFICATION
Product identifier
Product Code R21-2995
Product Name APPETITE SUPPRESS NAT
Recommended use of the chemical and restrictions on use
Recommended use Aromatic Ingredient(s). For Industrial Use Only. Restrictions on use Do not ingest as such. Avoid eye contact.
Details of the supplier of the safety data sheet Supplier
Robertet, Inc.
Fragrance Division
400 International Drive
Mount Olive, NJ 07828 USA
TEL: 201-405-1000
E-mail: regfrag@robertetusa.com
Emergency telephone number
Emergency Telephone Chemtrec 1-800-424-9300 (24 hrs) Outside of the USA and Canada (703) 527-3887. Collect calls accepted
2. HAZARDS IDENTIFICATION
Classification
Skin corrosion/irritation |
Category 2 |
Serious eye damage/eye irritation |
Category 2A |
Skin sensitization |
Category 1B |
Aspiration hazard |
Category 1 |
Flammable liquids |
Category 3 |
Hazards not otherwise classified (HNOC) Not applicable
Label elements
Signal word Danger Hazard statements Causes skin irritation Causes serious eye irritation May cause an allergic skin reaction May be fatal if swallowed and enters airways Flammable liquid and vapor |
Wash face, hands and any exposed skin thoroughly after handling
Avoid breathing dust/fume/gas/mist/vapors/spray
Contaminated work clothing must not be allowed out of the workplace
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ ventilating / lighting/equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Wear protective gloves/eye protection/face protection
Precautionary Statements - Response
Specific treatment (see supplemental first aid instructions on this label)
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention
If skin irritation or rash occurs: Get medical advice/attention
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower
Wash contaminated clothing before reuse
IF SWALLOWED: Immediately call a POISON CENTER or doctor
Do NOT induce vomiting
In case of fire: Use CO2, dry chemical, or foam to extinguish
Precautionary Statements - Storage
Store locked up
Store in a well-ventilated place. Keep cool
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Other information
Harmful to aquatic life with long lasting effects. Very toxic to aquatic life.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical name |
CAS No |
Weight-% |
GHS Classification |
Limonene |
5989-27-5 |
70 - 80 |
Flam. Liq. 3 (H226) Skin Irrit. 2 (H315) Skin Sens. 1B (H317) Asp. Tox. 1 (H304) Aquatic Acute 1 (H400) Aquatic Chronic 3 (H412) |
Menthol |
89-78-1 |
10 - 20 |
Flam. Liq. 4 (H227) Acute Tox. Oral 5 (H303) Skin Irrit. 2 (H315) Eye Irrit. 2B (H320) Aquatic Acute 3 (H402) |
Menthone |
10458-14-7 |
5.0 - 10 |
Flam. Liq. 4 (H227) Acute Tox. Oral 5 (H303) Skin Irrit. 2 (H315) Skin Sens. 1B (H317) |
Aquatic Acute 3 (H402) |
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d,l-Isomenthone |
491-07-6 |
1.0 - 5.0 |
Flam. Liq. 4 (H227) Acute Tox. Oral 5 (H303) Skin Irrit. 2 (H315) Skin Sens. 1B (H317) Aquatic Acute 3 (H402) |
beta-Myrcene |
123-35-3 |
1.0 - 5.0 |
Flam. Liq. 3 (H226) Skin Irrit. 2 (H315) Eye Irrit. 2A (H319) Asp. Tox. 1 (H304) Aquatic Acute 1 (H400) Aquatic Chronic 2 (H411) |
Menthyl acetate |
89-48-5 |
1.0 - 5.0 |
Flam. Liq. 4 (H227) Aquatic Acute 2 (H401) Aquatic Chronic 2 (H411) |
Eucalyptol |
470-82-6 |
1.0 - 5.0 |
Flam. Liq. 3 (H226) Acute Tox. Oral 5 (H303) Skin Irrit. 3 (H316) Skin Sens. 1B (H317) |
beta-Caryophyllene |
87-44-5 |
0.1 - 1.0 |
Skin Sens. 1B (H317) Asp. Tox. 1 (H304) Aquatic Chronic 4 (H413) |
Linalool |
78-70-6 |
0.1 - 1.0 |
Flam. Liq. 4 (H227) Acute Tox. Oral 5 (H303) Skin Irrit. 2 (H315) Eye Irrit. 2A (H319) Skin Sens. 1B (H317) Aquatic Acute 3 (H402) |
beta-Pinene |
127-91-3 |
0.1 - 1.0 |
Flam. Liq. 3 (H226) Skin Irrit. 2 (H315) Skin Sens. 1B (H317) Asp. Tox. 1 (H304) Aquatic Acute 1 (H400) Aquatic Chronic 1 (H410) |
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
Description of first aid measures
General advice Show this safety data sheet to the doctor in attendance. Immediate medical attention is
required.
Inhalation Aspiration into lungs can produce severe lung damage. If breathing has stopped, give
artificial respiration. Get medical attention immediately. Remove to fresh air. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. If breathing is difficult, (trained personnel should) give oxygen. Get immediate medical advice/attention. Delayed pulmonary edema may occur.
Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Do not rub affected area. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. May cause an allergic skin reaction. In the case of skin irritation or allergic reactions see a physician.
Ingestion ASPIRATION HAZARD IF SWALLOWED - CAN ENTER LUNGS AND CAUSE DAMAGE.
Do NOT induce vomiting. If vomiting occurs spontaneously, keep head below hips to prevent aspiration. Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. Get immediate medical advice/attention.
Self-protection of the first aider Remove all sources of ignition. Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. Use personal protective equipment as required. See section 8 for more information. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. Avoid contact with skin, eyes or clothing.
Most important symptoms and effects, both acute and delayed
Symptoms Itching. Rashes. Hives. Difficulty in breathing. Coughing and/ or wheezing. Dizziness. May cause redness and tearing of the eyes. Burning sensation.
Indication of any immediate medical attention and special treatment needed
Note to physicians May cause sensitization in susceptible persons. Treat symptomatically. Because of the danger of aspiration, emesis or gastric lavage should not be employed unless the risk is justified by the presence of additional toxic substances.
5. FIRE-FIGHTING MEASURES |
|
Suitable Extinguishing Media |
Dry chemical. Carbon dioxide (CO2). Water spray. Alcohol resistant foam. |
Large Fire |
CAUTION: Use of water spray when fighting fire may be inefficient. |
Unsuitable extinguishing media |
Do not scatter spilled material with high pressure water streams. |
Specific hazards arising from the chemical |
Risk of ignition. Keep product and empty container away from heat and sources of ignition. In the event of fire, cool tanks with water spray. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Product is or contains a sensitizer. May cause sensitization by skin contact. |
Explosion data Sensitivity to mechanical impact None. Sensitivity to static discharge Yes. Special protective equipment for Firefighters should wear self-contained breathing apparatus and full firefighting turnout fire-fighters gear. Use personal protection equipment. |
|
6. ACCIDENTAL RELEASE MEASURES |
Personal precautions, protective equipment and emergency procedures
Personal precautions |
Evacuate personnel to safe areas. Use personal protective equipment as required. See section 8 for more information. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Keep people away from and upwind of spill/leak. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Pay attention to flashback. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. |
Other information |
Ventilate the area. Refer to protective measures listed in Sections 7 and 8. |
Methods and material for containment and cleaning up
Methods for containment |
Stop leak if you can do it without risk. Do not touch or walk through spilled material. A vapor suppressing foam may be used to reduce vapors. Dike far ahead of spill to collect runoff water. Keep out of drains, sewers, ditches and waterways. Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. |
Methods for cleaning up |
Take precautionary measures against static discharges. Dam up. Soak up with inert |
absorbent material. Pick up and transfer to properly labeled containers.
7. HANDLING AND STORAGE
Precautions for safe handling |
|
Advice on safe handling |
Use personal protection equipment. Avoid breathing vapors or mists. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use grounding and bonding connection when transferring this material to prevent static discharge, fire or explosion. Use with local exhaust ventilation. Use spark-proof tools and explosion-proof equipment. Keep in an area equipped with sprinklers. Use according to package label instructions. Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash before reuse. |
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep container tightly closed in a dry and well-ventilated place. Keep away from open flames, hot surfaces and sources of ignition.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION |
||||
Control parameters Exposure Limits |
The following ingredients are the only ingredients of the product above the cut-off level (or level that contributes to the hazard classification of the mixture) which have an exposure limit applicable in the region for which this safety data sheet is intended or other recommended limit. At this time, the other relevant constituents have no known exposure limits from the sources listed here |
|||
Chemical name |
ACGIH TLV |
OSHA PEL |
NIOSH IDLH |
|
beta-Pinene 127-91-3 |
dermal sensitizer TWA: 20 ppm |
- |
- |
Appropriate engineering controls
Engineering controls Showers
Eyewash stations
Ventilation systems.
Individual protection measures, such as personal protective equipment
Eye/face protection |
Tight sealing safety goggles. |
Hand protection |
Wear suitable gloves. Impervious gloves. |
Skin and body protection |
Wear suitable protective clothing. Long sleeved clothing. Chemical resistant apron. Antistatic boots. |
Respiratory protection |
No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. |
General hygiene considerations |
Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is |
recommended. Wash hands before breaks and immediately after handling the product.
Wear suitable gloves and eye/face protection. Avoid contact with skin, eyes or clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES |
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Information on basic physical and chemical properties Physical state Oily liquid |
||
Appearance |
Yellow to dark yellow |
|
Odor |
Perfume odor |
|
Odor threshold |
No information available |
|
Property pH Melting point / freezing point Boiling point / boiling range Flash point Evaporation rate Flammability (solid, gas) Vapor Pressure (mm Hg @ 20°C): Vapor density Relative density Specific Gravity @ 20/20 °C Solubility(ies) Water solubility Solubility in other solvents Partition coefficient Autoignition temperature Decomposition temperature Viscosity |
Values > 35 °C 53 °C / 127 °F 0.8540 - 0.8740 |
Remarks • Method No information available No information available No information available CC (closed cup) No information available No information available No information available No information available No information available RTM-101 No information available No information available No information available No information available No information available No information available |
Other information Explosive properties |
No information available |
|
Oxidizing properties |
No information available |
|
10. STABILITY AND REACTIVITY |
Reactivity No information available.
Chemical stability Stable under normal conditions.
Possibility of hazardous reactions None under normal processing.
Conditions to avoid Heat, flames and sparks.
Incompatible materials Strong acids. Strong bases. Strong oxidizing agents.
Hazardous decomposition products None known based on information supplied.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information |
. |
||
Inhalation |
Specific test data for the substance or mixture is not available. Aspiration into lungs can produce severe lung damage. May cause pulmonary edema. Pulmonary edema can be fatal. May cause irritation of respiratory tract. |
||
Eye contact |
Specific test data for the substance or mixture is not available. Irritating to eyes. (based on components). Causes serious eye irritation. |
||
Skin contact |
May cause sensitization by skin contact. Specific test data for the substance or mixture is not available. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. (based on components). Repeated exposure may cause skin dryness or cracking. Causes skin irritation. |
||
Ingestion |
Specific test data for the substance or mixture is not available. Potential for aspiration if swallowed. May cause lung damage if swallowed. Aspiration may cause pulmonary edema and pneumonitis. May be fatal if swallowed and enters airways. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. |
Symptoms related to the physical, chemical and toxicological characteristics
Symptoms Itching. Rashes. Hives. Difficulty in breathing. Coughing and/ or wheezing. Dizziness.
Redness. May cause redness and tearing of the eyes.
Acute toxicity
Numerical measures of toxicity
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) > 5000 mg/kg
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation Classification based on data available for ingredients. Irritating to skin.
Serious eye damage/eye irritation Classification based on data available for ingredients. Causes serious eye irritation.
Respiratory or skin sensitization May cause sensitization by skin contact.
Germ cell mutagenicity No information available. Carcinogenicity No information available.
12. ECOLOGICAL INFORMATION
This product contains a chemical which is listed as a marine pollutant according to DOT.
Ecotoxicity
Very toxic to aquatic life. Harmful to aquatic life with long lasting effects.
Persistence and degradability No information available.
Bioaccumulation
There is no data for this product.
Other adverse effects
No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods |
|
Waste from residues/unused products |
Should not be released into the environment. Dispose of in accordance with local regulations. Dispose of waste in accordance with environmental legislation. |
Contaminated packaging Empty containers pose a potential fire and explosion hazard. Do not cut, puncture of weld containers.
14. TRANSPORT INFORMATION |
|
DOT |
Not regulated |
Marine pollutant |
This product contains a chemical which is listed as a marine pollutant according to DOT (Limonene) |
IATA/ICAO UN/ID no |
1266 |
Proper shipping name |
Perfumery products |
Hazard class |
3 |
Packing group |
III |
IMDG/IMO UN number |
1266 |
UN proper shipping name |
Perfumery products |
Transport hazard class(es) |
3 |
Packing group |
III |
EmS-No |
F-E, S-D |
15. REGULATORY INFORMATION |
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312 Hazard Categories
Should this product meet EPCRA 311/312 Tier reporting criteria at 40 CFR 370, refer to Section 2 of this SDS for appropriate classifications.
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
16. OTHER INFORMATION
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet